Abstract
In the title compound, [CoCl2(C10H8N2S)2]n, the CoII atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octahedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the CoII centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intramolecular C—H⋯N and C—H⋯Cl hydrogen bonds.
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