Abstract

The title compound, [Na(NO3)(C3H7NO2)]n, was obtained unintentionally as the product of an attempted reaction of sodium molybdate in aqueous solution and the amino acid l-alanine (ala), in order to obtain a γ-type octa­molybdate, Na4[Mo8O26(ala)2].18H2O, coordinated by l-alanine. The coordination geometry around the Na atom can be considered as trigonal–bipyramidal, with three bidentate nitrate anions coordinating through their O atoms and two l-alanine mol­ecules each coordinating through one carboxylate O atom.

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