Abstract
Complexation of thallium(I) with ethane-1,2-dithiol has been studied polarographically in 25% ethanol, 0.5M-NaClO4, 0.01M-HClO4 and 0.002% Triton X-100. Thallium in presence of ethane-1,2-dithiol, reduces reversibly at d.m.e. and the plateau current is diffusion-controlled. The successive formation of two complexes, 1∶1 and 1∶2, is indicated byDeford andHume's method. The overall changes in the thermodynamic parameters viz. ΔG, ΔH, ΔS accompanying complexation reactions have also been reported.
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