Abstract

This paper deals with the effect of the polarity and gap geometry on DC breakdown voltage characteristics of a point-to-plane gap in supercritical carbon dioxide (SC CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> ) that is required to design a plasma reactor. In the experiments, the gap width d and the curvature radius of the point tip r were changed in the range of 80 to 300 mum and 50 to 170 mum respectively, and the CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> state was controlled within the gas, liquid, and SC phases. The experimental results showed that a remarkable polarity effect appeared under certain gap conditions. As a result, it was found that negative polarity and a higher stressed electrode are desired conditions for the dc plasma reactor since an active corona supplying rich chemical radicals appears in SC CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> under such conditions.

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