Abstract

Preparation de radicaux carbamoyles et α-N-amidoalkyles. Ces radicaux attaquent selectivement des bases heteroaromatiques protonees, comme la quinoxaline ou la lipidine, en position α. On suggere des mecanismes redox en chaine. On discute de l'importance des effets polaires dans les reactions d'enlevement d'hydrogene, de substitution aromatique et d'oxydation par les sels de Fe(III)

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