Plasmonic heating induced by Au nanoparticles for quasi-ballistic thermal transport in multi-walled carbon nanotubes.

Abstract

The plasmon resonances of nanostructures enable wide applications from highly sensitive sensing to high-resolution imaging, through the improvement of photogeneration rate stimulated by the local field enhancement. However, quantitative experimental studies on the localized heating and the thermal transport process in the vicinity of plasmonics are still lacking because of the diffraction limit in conventional optothermal methodologies. In this work, we demonstrate an approach based on Raman thermometry to probe the near-field heating caused by plasmonics. An array of Au nanoparticles (AuNPs) fabricated by the template-assisted method is used to generate the near field effect. Multi-walled carbon nanotubes (MWCNTs) dispersed on the AuNPs are employed to quantify the near-field heating from their Raman peak shifts. Results show that the temperature rise in MWCNTs on AuNPs is much higher than that in a control group under the same laser irradiation. Further analysis indicates that the enhanced photon absorption of MWCNTs attributed to plasmon resonances is partially responsible for the different heating effect. The nonuniform thermal hot spots at the nanoscale can result in the quasi-ballistic thermal transport of phonons in MWCNTs, which is another reason for the temperature rise. Our results can be used to understand plasmonic heating effects as well as to explore quasi-ballistic thermal transport in carbon-based low-dimensional materials by tailoring the geometry or size of plasmonic nanostructures.