Plants transpiration-inspired antibacterial evaporator with multiscale structure and low vaporization enthalpy for solar steam generation

Abstract

Solar-driven vapor generation by localized solar heating of a photothermal material is an environmentally friendly approach for seawater desalination and wastewater purification. In this work we designed a novel bionic evaporator, inspired by plant transpiration in nature, to realize highly efficient solar vapor generation. The plant transpiration inspired three-dimensional structure has a hydrophilic cellulose skeleton with high porosity and low thermal conductivity, and decorated with photothermal polypyrrole (PPy) that self-organize as nano branches and leaves exhibiting excellent photothermal conversion capacity. The cellulose skeleton has microchannels that facilitates water transport and reduces the water evaporation enthalpy. PPy nano branches and leaves can not only efficiently absorb and convert sunlight, but the thermal gradient distribution in this microstructure induces Marangoni convection which guarantees efficient water transportation in evaporative regions. Moreover, the coupling of external wind fields further enhances the rate of vapor escape. The as-fabricated vapor generator based on the bionic structure achieved an impressive high evaporation rate of 2.05 kg m−2 h−1 under one sun (1 kW m−2) irradiation, with the solar thermal conversion efficiency up to 97.7%. A significantly higher water vapor generation rate of 2.9 kg m−2 h−1 is obtained under one sun irradiation at a wind speed of 2 m s−1. In addition, the evaporator has excellent photothermal antibacterial activity against both E. coli and S. aureus. This bionic evaporator offers a potential low-cost and highly efficient water purification technology that could help mitigate the global water crisis.