Abstract
A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline, nphen = 5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated.
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