Abstract

The experimental curves of the photochromic properties of glasses as a function of their composition and the coordination state of the components were analyzed based on coordination theory and the concept of acid-base ratios. It was hypothesized that the notion concerning the formation of unstable boron-based complexes containing active photosensitive components can also be extended to the coordination state of aluminum. A correlation was demonstrated between the photochromic properties of copper halide glasses and the basicity coefficient, which generally characterizes the acid-base properties of glass.

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