Abstract
AbstractBlending effects of thermoplastic polyurethane based on polycaprolactone diol, PU (PCL diol), and poly (ϵ‐caprolactone) (PCL) on the rheological properties and morphological behavior of the solvent‐cast blends were investigated by parallel plate rheometer. The amount of PCL was varied from 20 to 50% by weight. Fourier transform infrared (FTIR) results showed existence of hydrogen bonding in PU/PCL blends. From FTIR, we also found the increase of PCL composition tends to reduction of intermolecular hydrogen bonding and enhancing of microphase separation in blends. Differential scanning calorimetry (DSC) indicated that these blend systems are partially miscible. Based on rheological characterization, decrease can be seen in the moduli, zero shear viscosity and plateau modulus of blends, as compared with net PU. Using Cole‐Cole plots and composition dependencies of η0 and the other viscoelastic functions expressed variation of morphology of blends due to increase of PCL content. Frequency sweep tests on PU/PCL (80/20) at five temperatures showed validity of time‐temperature superposition in this blend. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
