Abstract
A combustion synthesis method has been developed for synthesis of Eu2+ doped CaAlSiN3 phosphor and its photoluminescence properties were investigated. Ca, Al, Si, and Eu2O3 powders were used as the Ca, Al, Si and Eu sources. NaN3 is added as the nitrogen source in the interior part of reactants and also as a reducing agent. While NH4Cl is added for catalysis of the synthesis reaction. These powders were mixed and pressed into a compact which was then wrapped up with an igniting agent (i.e.,Mg+Fe3O4). The compact was ignited by electrical heating under a N2 pressure of 0.2-1.0MPa. Effects of these experimental parameters on the photoluminescence properties and product yield were investigated. The synthesized CaAlSiN3:Eu2+ phosphor absorbs light in the region of 200-600 nm and shows a broad band emission in the region of 500-800 nm due to the 4f65d1→4f7 transition of Eu2+. The peak emission intensity is ~106 % of a commercially available phosphor, YAG:Ce3+(P46-Y3), and the peak emission wavelength ranges from 610 to 680 nm depending on the Eu2+ concentration upon excitation at 460nm.The synthesized phosphor also shows excellent thermal and chemical stability and thus has a potential application as a red phosphor for white LED lighting.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
