Abstract
In the present work, stratified WO3/ZnO thin films have been prepared by simple chemical spray pyrolysis technique. The structural, morphological, compositional and photoelectrocatalytic properties of the stratified WO3/ZnO thin films are studied. The photoelectrochemical (PEC) study shows that, both short circuit current (Isc) and open circuit voltage (Voc) are (Isc=1.023mA and Voc=0.980V) relatively high at 40ml spraying quantity of ZnO solution on pre-deposited WO3 thin films. XRD analysis reveals that stratified WO3/ZnO thin films are polycrystalline with monoclinic and hexagonal crystal structures for WO3 and ZnO respectively. The specific surface area of the stratified WO3/ZnO thin film is found to be 48.12m2g−1. The enhanced photoelectrocatalytic activity of stratified WO3/ZnO is mainly due to the suppressing the recombination of photo generated electron-hole pairs. The end result shows that the degradation percentage of phthalic acid (PA) using stratified WO3/ZnO photo electrode has reached 63.63% after 320min. under sunlight illumination. The amount of mineralization of phthalic acid is studied with the help of chemical oxygen demand (COD) measurement.
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