Abstract
Chiral phosphorus-based structures were investigated as N-activating groups for anodic oxidation and as chiral inductors. This first study presents the results obtained for pyrrolidine, with allyltrimethylsilane as a standard nucleophile. The methoxylated compounds were obtained in excellent yields (82-98%). The diastereoselectivity of the alkylation step (18-66%) is discussed with regard to the chiral auxiliary.
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