Abstract
Abstract Phosphorus-containing crown-ethers functionalized by heterocycle fragments have essential advantages over the usual ones. The introduction of structural units of indoles, pyrroles and indolizines to phosphorus atom of the macrocyclic chain is capable to change lipophilic, complexing, biological and other properties of the initial crown-ethers. For synthesis of such compounds we have used dihalidophosphines obtained by direct substitution of the electron-rich aromatic compounds with phosphorus (III) halides. As a result, series of highly efficient macrocyclic compounds of a nowel type have been obtained.
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