Abstract

The kinetics of phase transformations in medium-carbon forging steels (MCFS) have been modeled based on CALPHAD multicomponent thermodynamics and the classical nucleation-growth theory. New treatments include the time dependency of parabolic growth rate of proeutectoid ferrite (α) , which account for the soft impingement effect by carbon enrichment in austenite (γ). And a potential transition of γ/α interface equilibrium has also been considered depending on temperatures and velocity of the moving interface. To make a realistic prediction of the onset of pearlite (P) transformation, a normal distribution of γ grain size has been assumed and successive α→P transformation kinetics in each grain size have been summated. The developed program coupled with thermodynamic solver, 'ThermoCalc', calculated the isothermal kinetics of MCFS and has been found to predict well the effect of minor difference of chemical composition / holding temperatures.

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