Abstract
Ti-Cr alloys have been laser deposited from powder feedstock consisting of a blend of elemental powders using the laser-engineered net-shaping (LENS) process. The microstructure of the as-deposited Ti-Cr alloys primarily consists of a metastable bcc matrix of β-Ti(Cr) with precipitates along the grain boundaries. The grain-boundary precipitates have been identified to be of three types, essentially pure hcp Ti, an alloyed hcp phase designated α-Ti(Cr), and the C14 TiCr2 Laves phase. Initial stages of decomposition, visible within the β matrix, suggest a spinodal clustering process resulting in a fine dispersion of second phases. Diffraction studies have revealed the presence of fine precipitates of α within the β matrix. The evidence for the precipitation of the metastable ω phase within the β matrix is not strong. The phase evolution in the LENS-deposited Ti-Cr alloy has been discussed in the context of rapid solidification and the enthalpy of mixing of the elemental powders.
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