Abstract

Abstract The thermodynamics of binary alloy phase diagrams of ascending and minimum types is shown to lead to a rather direct relation between the ratio of the slopes of the liquidus and the solidus curves, at a given temperature T, and the ratio <(δc)2 1(δc)2 s of the concentration fluctuations in the liquid and the solid solutions. The latent heats of the two pure components also enter in a direct manner, as could have been anticipated from the results of ideal solution theory

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