Abstract

In order to study dye-matrix interactions and dynamical properties in simple model systems, we incorporated free-base phthalocyanine in solid matrices of argon, krypton and xenon. Using a novel cryostat, the sample, which was produced under vacuum conditions, could be immersed in liquid helium, allowing temperatures down to 1.5 K. The assumptions of stochastic models describing the inhomogeneous broadening could be verified to a large extent by these model systems. Access to dynamical information is gained through hole burning experiments.

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