Persistent organic pollutants PCNs and PBDEs in sediments from coastal waters of Qingdao, Shandong Peninsula

Abstract

Thirty-one congeners of polychlorinated naphthalenes (PCNs) and 21 congeners of polybrominated diphenylethers (PBDEs)in surface sediments at 5 stations and one mussel sample from Qingdao coastal waters were analyzed. The maximum contents occur at the station near the Haibo River mouth. The total PCNs contents are in the range of 212–1209 pg/g dw, dominated by tri-Cl CN. The total PBDEs contents are in the range of 117–5510 pg/g dw, dominated by tri-to hexa-BrBDEs. The local sources of PCNs are likely from combustion processes such as incinerations and coal burnings. The sources of PBDEs are molecular diffusion from the materials containing them. Except for the area near the river mouth where is affected by the sewage sludges, an important source of PCNs and PBDEs in this area is believed to be the atmospheric deposition. Mussels enrich PCNs and PBDEs relative to the sediments. The total TEQs of PCNs in mussels are lower than the total TEQs of PCBs.