Abstract
Imidacloprid is a systemic insecticide which gives effective control of plant and leaf hoppers in rice. The persistence and metabolism of imidacloprid in paddy leaves, rice grains, bran, straw and husk were studied following two applications of imidacloprid (Confidor 17.8 SL) @ 20 and 80g a.i. ha(-1) at an interval of 10days. Samples of paddy leaves were collected at various time intervals. The samples of rice grains, bran, straw and husk were collected at the time of harvest. The limit of quantification of imidacloprid and its metabolites was worked out to be 0.01mgkg(-1). The maximum residues of imidacloprid and its metabolites in paddy leaves after 0day (1h after last spray) of its application @ 20 and 80g a.i. ha(-1) were found to be 4.57 and 13.94mgkg(-1), respectively. These residues could not be detected after 60 and 90days following last application of imidacloprid at lower and higher dosages, respectively. In rice, olefin metabolite was found to be the main constituent, followed by nitroguanidine, urea, 5-hydroxy, chloronicotinic acid and nitrosimine. The samples of rice grains, bran, straw and husk did not reveal the presence of imidacloprid or its metabolites following its application at both the dosages at harvest.
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More From: Bulletin of Environmental Contamination and Toxicology
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