Abstract

An experimental method for measuring the permeability coefficient K for the permeation of air through black foam films is described. A series of measurements of K for sodium dodecyl sulfate plus sodium chloride aqueous solutions have been performed. Experimental results concerning the dependences of K on surfactant concentration C, NaCl concentration C e1 and temperature T are reported. A stepwise decrease in permeability K at the transition from common black film (CBF) to Newton black film (NBF) has been found, the K values of the thinnest NBF being 2–3 times lower than those of the essentially thicker CBE. The results show that gas permeation through black foam films is mainly determined by the properties of the surfactant layers: monolayers in the case of CBFs and a bilayer in the case of NBFs. The experimental results concerning the permeability of CBFs are discussed on the basis of theories of gas permeation through monomolecular layers.

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