Performance of dispersed oil and suspended sediment during the oil-sediment aggregation process

Abstract

Oil-sediment aggregation is an important transport and transformation process of spilled oil, which has been considered as a pathway of spill remediation. This work focused on the individual performance of dispersed oil and sediment during the aggregation process. Dispersion of three oils was first tested and validated in a water tank. An approach of estimating the mass variation of the sediment that has participated in forming the oil-sediment aggregates (OSAs) has been developed by density analysis. Results indicated that the density of the formed OSAs increases during the aggregation. In the context of remediation, it takes longer for sediment to reach equilibrium than for dispersed oil, especially under high mixing energy at a large sediment concentration, which results in the formation of dense OSAs, as well as high aggregation degree and rate. Roncador oil possesses a relatively high capability of capturing sediment to form dense OSAs, especially at an initial sediment concentration of over 150 mg/L. Oil sinking efficiency and the characteristic change rate of aggregated oil mass seem to be proportional to oil dispersion efficiency, and decrease with the mean size of dispersed oil droplets. The process of aggregation can further promote the dispersion of oil into water column. This study also provides fundamental data for the formation kinetics of OSAs.