Performance Investigation of PSF-nAC Composite Ultrafiltration Membrane for Protein Separation.

Abstract

As a promising wastewater treatment technology, ultrafiltration membranes face challenges related to fouling and flux reduction. To enhance these membranes, various strategies have been explored. Among them, the incorporation of nano-activated carbon (nAC) powder has emerged as an effective method. In this study, composite polysulfone (PSF) ultrafiltration membranes were fabricated using nAC powder at concentrations ranging from 0 to 8 wt.%. These membranes underwent comprehensive investigation, including assessments of membrane morphology, hydrophilicity, pure water flux, equilibrium water content, porosity, average pore size, and protein separation. The addition of activated carbon improved several desirable properties. Specifically, the hydrophilicity of the PSF membranes was enhanced, with the contact angle reduced from 69° to 58° for 8 wt.% of nAC composite membranes compared to the pristine PSF membrane. Furthermore, the water flux test revealed that 6 wt.% activated carbon-based membranes exhibited the highest flux, with a nearly 3 times improvement at 2 bar. Importantly, this enhancement did not compromise the protein rejection. Additionally, the introduction of nAC had a significant effect on the membrane's pore size by improving lysozyme rejection up to 40%. Overall, these findings will guide the selection of the optimal concentration of nAC for PSF ultrafiltration membranes.