Abstract
In the title mononuclear complex, [Zn(ClO4)(C17H11N3O)2]ClO4, the ZnII ion is coordinated in a distorted octahedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10)° for the tridendate PP ligand and 73.55 (6)° for the bidentate PP ligand. Within the molecule there is a weak π–π interaction between the pyridine ring of the bidentate ligand and the 1,10-phenanthroline ring system of the tridendate ligand with a centroid–centroid distance of 3.6383 (19) Å.
Highlights
In the title mononuclear complex, [Zn(ClO4)(C17H11N3O)2]ClO4, the ZnII ion is coordinated in a distorted octahedral geometry
The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10) for the tridendate PP ligand and 73.55 (6) for the bidentate PP ligand
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH2853)
Summary
Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.004 A; R factor = 0.044; wR factor = 0.130; data-to-parameter ratio = 12.8. Crystal data [Zn(ClO4)(C17H11N3O)2]ClO4 Mr = 810.85 Monoclinic, P21=n a = 12.998 (2) Ab = 16.741 (3) Ac = 14.680 (3) A = 100.068 (2)
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