Abstract
Three complexes [Fe(L)2](ClO4)2 (1)、[Ni(L)2](ClO4)2 (2) and [Co(L)2](ClO4)2 (3) were synthesized by the reaction of N,N’-(4-methylpyridin-2-yl)pyrazine-2,6-diamine (L) with Fe(ClO4)2·6H2O, (Ni(ClO4)2·6H2O or Co(ClO4)2·6H2O) at room temperature, respectively. They were characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The catalytic behavior of the complexes for the synthesis of propylene carbonate from propylene oxide and carbon dioxide were studied. The results show that all of them showed excellent catalytic activities with TOF as high as 2104 h-1, 2824 h-1 and 2605 h-1, respectively. Complex 2 that exhibit higher catalytic activity was taken to explore the influence of time, pressure and temperature to optimize the reaction condition in detail.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
