Abstract
AbstractCopolymers with a 2:1 regulated sequence of N‐phenylmaleimide with β‐pinene units (AAB‐type repeating units) are produced during radical copolymerization. The monomer reactivity ratios are determined using the penultimate unit model, and it is demonstrated that they vary depending on the solvent used (tetrahydrofuran, 1,2‐dichloroethane, 2,2,2‐trifluoroethanol, and perfluoro‐tert‐butanol) and the copolymerization temperature (0–100 °C). The interaction of the PhMI repeating units with solvents lead to the production of the 2:1 controlled sequence and a significant change in the relative reactivity of the PhMI radicals by polar and steric effects.
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