Abstract
A research has been undertaken to increase the cold resistance of upper leather by decreasing its water absorption ability. Fluorinated acrylic polymer, a water repellent substance, was added at fatliquoring and finishing stages of upper leather with different concentrations levels. Research findings showed that an increase in the water-repellent concentration, i.e. by 5; 7.5; 10; 12.5; and 15%, result in increases in tensile strength, tearing strength, and elongation at break, whereas decreases in water absorption ability. No significant differences for the other physical properties such as water vapor absorption, water vapor permeability, and flexing resistance and they met the standard for shoe leather. Results of scanning electron microscopy indicated an increased thin layer of water repellent on leather fibers as the water-repellent concentration increased. The leather fibers looked smoother, glistened, and thicker. This indicates the penetration of water repellent onto leather fibers. Keywords: water absorption, water repellent, cold resistance, upper leather.
Highlights
ABSTRAK Penelitian telah dilakukan untuk meningkatkan ketahanan terhadap suhu dingin kulit atasan sepatu dengan menurunkan daya serap airnya
A research has been undertaken to increase the cold resistance of upper leather by decreasing its water absorption ability
Research findings showed that an increase in the water-repellent concentration
Summary
Bahan penelitian yaitu kulit sapi wet blue, wetting agent (Mulgan BW), natrium formiat, krom sintan, natrium bikarbonat, neutralising syntan, resin akrilik, Tanicor SGN, Sincal MS, cat dasar, Derminol SBJ, Derminol SPE, anti jamur, asam formiat, fluorinated acrylic polymer, bahan finishing (RA2, RU3906, BI 372, FI11250, Penetrator, Pigmen), dan bahan untuk top coating (lak netral, thinner super, dan KS). Kemudian dilakukan penyamakan ulang dengan menggunakan bahan penyamak resin akrilik dan Tanicor SGN dilanjutkan dengan pengecatan dasar menggunakan cat dasar warna hitam dan penetrator Sincal MS. Proses peminyakan dengan bahan fatliquor Derminol SBJ, Dermenol SPE, dan anti jamur, setelah fiksasi dengan FA, ditambahkan water repellent jenis fluorinated acrylic polymer. Pengujian analisis kimia dan fisika kulit atasan sepatu meliputi uji: penyerapan air, kekuatan tarik, kemuluran, kekuatan sobek, WVP, WVA, ketahanan bengkuk (ISO, 2007), dan morfologi
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