Abstract

AbstractThe cover picture shows the serendipitous transformation of the yellow into the dark orange triple‐decker sandwich complex by air. The unique B=CH2 group formed strongly leans toward one of the metal atoms. Non‐equivalence of the Cp*Ru groups suggests a bridge inversion, which does not occur below 70 °C. At higher temperatures the signals of the Cp* protons broaden, but coalescence is not reached in toluene. Details are discussed in the article by M. Enders, A. R. Kudinov, W. Siebert et al. on p. 2911 ff.

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