Paraffin/graphite/boron nitride composite as a novel phase change material for rapid heat absorption in battery thermal management technology

Abstract

Phase change material (PCM) cooling is widely employed in the thermal management of compact battery packs. Thermal protection triggered by rapid temperature rise shortens the effective discharge time in high-rate discharge, making it essential to prepare PCM that rapidly absorbs heat at high temperatures. However, research on the thermal absorption performance and insulating properties of PCM at high-rate discharge remains limited. Herein, we innovatively propose a thermally conductive and insulating PCM with a wide phase transition temperature to address the overheating issue in batteries at 7 C, 8 C and 9 C discharge rates. The C236 consists of paraffin (PA236), graphite and boron nitride with a ratio of 6: 2: 2, which achieves outstanding thermal performance with a latent heat of up to 138.0 J/g and a high-volume resistivity of 1.6 × 108 Ω·m. It is found that at a discharge rate of 7 C, the C236 with a thickness of 3 mm effectively maintains the temperature below 80 °C. At discharge rates of 8 C and 9 C, the PCM significantly reduces the battery temperature by 26.9 % and 32.5 %, respectively, highlighting the rapid heat absorption capability at high temperatures. Furthermore, after four cycles at a 9 C discharge rate, the temperature differential of the battery remains below 5 °C. The low-cost PCM provides a new experimental reference for battery thermal management in high-rate discharge, with broad application prospects.