Abstract
The borylation of electron-deficient aryl chlorides with pinacolborane proceeded in the presence of Bu 4 NI and a catalytic amount of Pd(dba) 2 / bis(2-di-tert-butylphosphinophenyl) ether. The combination of NiCl 2 (dppp) catalyst and Bu 4 NBr was also efficient for the borylation of aryl chlorides.
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