Abstract
PdCl 2(PhNH 2) 2 catalyses the conversion of N, N′-diphenylurea into alkyl N-phenylcarbamate under CO and O 2 pressures at temperatures higher than 100 °C. The reaction rate and yields grow with increasing CO and O 2 pressures and in the presence of CuCl 2(PhNH 2) 2. The conversion is accomplished through the following reactions: ▪ Due to a side reaction, some amounts of carbon dioxide are also obtained.
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