Abstract
A series of zerovalent palladium complexes Pd(NN)(alkene) of bi- or tridentate nitrogen ligands of the general formula 6-R‘ ‘-C5H3N-(C(R‘)NR)-2 (R‘ ‘ = H, Me, CHNR‘; R‘ = H, Me; R = alkyl, aryl, or amino group) and dimethylfumarate (dmfu) have been prepared and were subsequently employed as precatalysts in the homogeneous stereoselective semihydrogenation of 1-phenyl-1-propyne. An X-ray structure of Pd(C5H4N-(C(Me)Ni-Pr)-2)(dmfu) was obtained. Whereas only relative small changes in substituents apply, the various complexes show very different stabilities under hydrogenation conditions. The complex Pd(C5H4N-(C(H)N(CH2)2OH)-2)(dmfu) exhibits a good selectivity for the (Z)-alkene but decomposes just before full conversion of the alkyne, whereas the complex Pd(C5H4N-(C(H)Ni-Pr)-2)(dmfu) exhibits a good selectivity and stability under hydrogenation conditions and is a suitable catalyst for the stereoselective hydrogenation of 1-phenyl-1-propyne to (Z)-1-phenyl-1-propene.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
