Abstract
Direct production of O( 3P) from the photodissociation of O 3 at 266 nm has been observed by time-resolved resonance fluorescence following laser flash photolysis. The quantum yield for O( 3P) production was determined to be 0.12 = 0.02 at this wavelength. This result confirms the qualitative observations of two previous photofragment studies and establishes an absolute value of Φ(O 1D)) = 0.88. This value has been used as a basis for normalizing relative quantum yields in the falloff region, and interpreting O( 1D) kinetics studies.
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