Abstract
The scope of metal loaded γ-Al2O3 materials as catalysts in the ozone initiated functionalisation of higher n-alkanes is investigated at moderate conditions (20 ± 1 °C and ∼1 atm). In the ozone initiated oxidation of the higher hydrocarbon, n-hexadecane with 0.5% Pd or Ni or V loaded γ-Al2O3 catalysts lead to the keto-isomers as main products, and organic acids as minor products. This paper emphasises the effect of γ-Al2O3 catalysts on the conversion, selectivity and reaction products during ozonation of n-hexadecane.
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