Abstract

Two types of WC–12Co coatings with different modifications were deposited on steel substrates using high velocity oxygen fuel (HVOF) spraying. The coated samples were oxidized at 550[Formula: see text]C and 650[Formula: see text]C in ambient atmosphere. Oxidation mass gain was measured by electronic balance. Phase composition and microstructure evolution of both coatings after oxidation were conducted by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Microhardness testing was performed before and after oxidation testing. The results showed that at 550[Formula: see text]C and 650[Formula: see text]C, the rare-earth modified WC–12Co coating has lower oxidation rates compared with the nanostructured WC–12Co coating. This might be due to the rare-earth modification coating reducing the porosity and oxygen diffusion in the coatings, therefore delaying the crack formation and propagation.

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