Abstract
(OsO4) [20816-12-0] O4Os (MW 254.20) InChI = 1S/4O.Os InChIKey = VUVGYHUDAICLFK-UHFFFAOYSA-N (K3Fe(CN)6) [13746-66-2] C6FeK3N6 (MW 329.27) InChI = 1S/6CN.Fe.3K/c6*1-2;;;;/q6*-1;+3;3*+1 InChIKey = BYGOPQKDHGXNCD-UHFFFAOYSA-N (cis dihydroxylation of alkenes; asymmetric dihydroxylation of alkenes, enynes, polyenes, and enol ethers) Physical Data: K3Fe(CN)6: orange crystals, d 1.89 g cm−3. See also Osmium Tetroxide. Solubility: K3Fe(CN)6: sol water (0.33 g mL−1 at 4 °C, 0.78 g mL−1 at 100 °C); slightly sol alcohol; decomposed by acids. Handling, Storage, and Precautions: K3Fe(CN)6: wear gloves and goggles. The aqueous solution decomposes slowly on standing. Store away from light. This reagent system should be used in a fume hood. See also Osmium Tetroxide.
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