Abstract
AbstractThe synthesis of 3‐aryl‐4‐nitrocyclohexanones has been achieved from the Morita–Baylis–Hillman adducts of β‐arylnitroethylenes. The strategy involves proline‐catalyzed diastereoselective intramolecular Michael addition to obtain 3,4‐trans‐disubstituted cyclohexanones. This method provides a facile access to (±)‐epibatidine analogues.
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