Abstract
Metallocycles occur in many cases as intermediates in processes which are catalyzed by transition metal complexes in the homogeneous phase. Frequently, it proved possible to isolate metallocycle complexes from catalytic experiments in crystalline form and to determine their structures by NMR-sepctroscopy as well as x-ray analysis. 3,4,5,7,9,11,12,13,14-membered metallocycles have been shown to be important in catalytic reactions involving alkynes, alkenes and 1,3-dienes. Isolated binuclear metallocycles suggest pathways for catalytic reactions involving two metal atoms.
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Schedule a callMore From: Organometallic Chemistry — 8: Plenary Lectures Presented at the Eighth International Conference on Organometallic Chemistry, Kyoto, Japan, 12–16 September 1977
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