Abstract

Sulfuranyl radicals are intermediates in a variety of addition/elimination reactions of sulfides, disulfanes, sulfoxylates and S-neterocycles as well as in the reduction of triorgano- and heteroorgano sulfonium salts. Their lifetimes — depending on their substutution pattern — range from < 1 μs to being thermally stabee in solution at room temperature with no reduction in concentration over severll months.

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