Organic geochemical characterization of Early-Mid-Holocene swamp deposits near the Neolithic settlement in Yenikapı-Istanbul: Assessment of environmental variability and anthropogenic impacts

Abstract

During the archaeological excavations in the Byzantine Theodosian harbor (Istanbul) a Holocene dark gray to black clay sequence was uncovered. This clay unit was deposited under anoxic conditions in a small swamp. Both wooden artifacts from the Neolithic period, but also dispersed organic matter were perfectly preserved within this sequence. The aim of this study was the assessment of environmental changes and anthropogenic impacts with the help of organic geochemical and isotopic characterization of organic matter in this clay unit. The age model, based on 14C data, showed that the clay was deposited during a period about from 11,100 to 7500 cal. years BP. Hydrogen Index values lower than 100 mgHC/gTOC, n-alkane distributions with maxima at nC29 or at nC31, a predominance of long-chain n-alkanes (C25–C33) and δ13Corg values around −24‰ to −27‰ suggest a predominantly terrestrial origin of organic matter from C3 plants. Obvious excursions of bulk δ13Corg and compound-specific δ13C and δD values of nC27, nC29, nC31, and nC33 are interpreted as indicators of changes in environmental and climatic conditions. Several shifts toward colder and warmer climatic conditions were identified and dated. Furthermore, two sudden changes in the hydrological regime were dated to 9000–8820 cal. years BP and to 8150–8050 cal. years BP toward wetter and drier conditions, respectively. Specific molecular organic geochemical indicators such as faecal sterols or a strong enrichment of δ15N caused by human impact could not be detected. Therefore, the swamp should not have been intensively affected by Neolithic people and/or respective indicators of their influence have been diluted due to the high sedimentation rate.