Abstract
The bond orbitals, associated with the Lewis structure, can be used as the basis set of canonical molecular orbitals. The concept of linear combination of bond orbitals for canonical molecular orbitals provides a link between two seemingly rival theories: valence bond theory and molecular orbital theory. The bond orbital basis set can reveal the character of the canonical molecular orbitals and the orbital delocalization due to intramolecular interaction. An index, called Lewis bond order, defined as the weight of bonding type bond orbitals, can be used to account for the bonding nature of the canonical molecular orbitals and thus also account for the vibrational structures of photoelectron spectroscopy. Each canonical molecular orbital of the molecules HCN and C 2H 2 may have several Lewis bond orders corresponding to several bonds in the Lewis structure.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.