Abstract

BackgroundAn increasing interest has been recently grown in the development of nearly perfect absorber materials for solar energy collectors and more in general for all the thermophotovoltaic applications.MethodsWide angle and broadband perfect absorbers with compact multilayer structures made of a sequence of ITO and TiN layers are here studied to develop new devices for solar thermal energy harvesting. Genetic Algorithms are introduced for searching the optimal thicknesses of the layers so to design a perfect broadband absorber in the visible range, for a wide range of angles of incidence from 0° to 50°, and for both polarizations.ResultsGenetic Algorithms allow to design several optimized structures with 6, 8, and 10 layers reaching a very high average absorbance of 97%, 99% and 99.5% respectively together with a low hemispherical total emissivity (<20%) from 200 °C till 400 °C.ConclusionsThe proposed multilayer structures use materials with high thermal stability, and high melting temperature, can be fabricated with simple thin film deposition techniques, appearing to have very promising applications in solar thermal energy harvesting.

Highlights

  • An increasing interest has been recently grown in the development of nearly perfect absorber materials for solar energy collectors and more in general for all the thermophotovoltaic applications

  • During last decade a huge interest has been grown in the development of nearly perfect absorber materials for applications as solar energy collectors, and, more in general, for all the thermophotovoltaic applications (TPV), so to increase the absorbed power for energy harvesting, storage and conversion as well as for the reprocessing of wasted heat in industrial processes [1, 2]

  • According to the methods described in the previous section, the figure of merit of the multilayer coating has been identified in the average absorbance Aav or better in the fitness function f = 1/(1-Aav)4 which is more appropriate to enhance the differences among quasi perfect absorbers

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Summary

Introduction

An increasing interest has been recently grown in the development of nearly perfect absorber materials for solar energy collectors and more in general for all the thermophotovoltaic applications. A new concept of perfect absorber is based on metamaterials where the enhancement of the absorption can be obtained thanks to the excitation of the surface plasmon resonance for example in gold and silver [6,7,8,9,10,11,12,13]. This can be achieved with structured metallic surfaces [14], microcavities [15], subwavelength hole arrays and opals [16, 17]. The realisation of broadband absorber metamaterials requires long and expensive procedures with multiple steps of film deposition, photoresist coating, etching and photoresist removing [28]

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