Abstract
Novel chiral dimeric models of isotactic (meso) and syndiotactic (dl) dyads of optically active methacrylic polymers containing in the side-chain the pyrrolidinyl group of one single configuration linked through the nitrogen atom to the azobenzene chromophore, have been synthesized by functionalization of 2,4-dimethylglutaric acids with known streoisomeric composition.Their characterization afforded the possibility to investigate the relationship between the chiroptical and spectroscopic properties displayed by the dimeric model compounds and those of the related homopolymeric derivatives with known main chain stereoregularity.In particular, the optical rotation values and circular dichroism spectra of the models allow to establish the contribution of main chain microtacticity to the overall optical activity of the polymeric derivative.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.