Optical responses from high-entropy alloys: experimental results and perspectives.

The production of carbon nano-materials by arc discharge under water or liquid nitrogen

The surface discharge of solid dielectric in liquid nitrogen has become one of the key problems in the development of high-temperature superconducting power devices. It is necessary to study the mechanism of surface discharge of the solid dielectric in liquid nitrogen. This article chose polytetrafluoroethylene and DW-3 epoxy resin as specimens, tested the surface discharge voltages of two kinds of specimens with different surface roughness under lightening impulse voltages in liquid nitrogen, and discussed the effect mechanism. The experimental results showed that the surface discharge voltage and discharge time of both materials in liquid nitrogen increased as the surface roughness increasing under lightning impulses. The surface roughness affects the surface discharge voltage of the solid dielectric in liquid nitrogen under lightning impulse, mainly in the charge left on the grinding surfaces of solid dielectrics, the heights of projections, and the creepage distance on the dielectric surfaces. The main discharge process is in the gasification path, and the effect of solid dielectric on surface discharge in liquid nitrogen is smaller. These reasons make the surface discharge in the liquid nitrogen less affected by the surface roughness. The results further explore the characteristics of surface discharge in liquid nitrogen and could provide methodological guidance to improve the surface discharge voltages in liquid nitrogen.

Single-step synthesis of nanocomposite of copper and carbon nanoparticles using arc discharge in liquid nitrogen

Carbon nanostructures synthesized by arc discharge between carbon and iron electrodes in liquid nitrogen

The synthesis of nanosheets through discharges in liquid nitrogen is observed for certain metals when employed as electrodes [1,2]. Various metals have been examined, with bismuth, lead, or zinc showing a propensity to form nanosheets. Other metals, such as silver or indium, also exhibit sheet formation but with smaller aspect ratios (width/thickness). Mixing metals is not only interesting to create alloys with new properties but also to understand how discharges work to enable the synthesis of these objects.Recently, we demonstrated that these structures can be grown not only in liquid nitrogen but also in water. This is attributed to the discharge primarily originating from the metallic vapor emitted by the electrodes, a consistent process in both liquids, as confirmed by time-resolved optical emission spectroscopy.We showcased that a pre-treatment, involving chemical etching by a Nital solution, significantly enhances the efficiency of nanosheet production, increasing it from almost zero to nearly 100%. We successfully identified the growth mechanism of nanosheets in the case of bismuth electrodes. These structures grow on the cathode with ion assistance, collecting in the bubble formed during the discharge. Upon the collapse of the bubble, they transfer into the liquid phase. Interestingly, the number density of nanoparticles produced under these conditions is either null or too weak to be evaluated.It is feasible to incorporate two different elements into 2D nanostructures by utilizing two electrodes. We achieved a mixture of lead and bismuth oxide by using electrodes composed of the respective elements. This capability is likely associated with the similar melting points and miscibility of both elements. Nanosheets exhibit thicknesses around 5-10 nm for widths ranging in the tens of micrometers.We anticipate that a more comprehensive understanding of the synthesis of these alloys will pave the way for the production of alloyed nanosheets incorporating other elements.[1] A. Hamdan, H. Kabbara, C. Noël, J. Ghanbaja, A. Redjaimia, T. Belmonte, “Synthesis of two-dimensional lead sheets by spark discharge in liquid nitrogen”, Particuology 40 (2018) 152–159[2] H. Kabbara, J. Ghanbaja, C. Noël, T. Belmonte, “Nano-objects synthesized from Cu, Ag and Cu28Ag72 electrodes by submerged discharges in liquid nitrogen”, Materials Chemistry and Physics 217 (2018) 371–378

Partial discharge (PD) in liquid nitrogen (LN2) insulation is a key issue in cryogenic or high-temperature superconducting power apparatus. In this letter, we experimentally demonstrate PD identification in LN2 using a fluorescent optical fiber sensor and compare its sensitivity to the conventional ultrahigh frequency (UHF) technique. The Corona inception voltage (CIV) in LN2 is studied under fundamental ac and harmonic ac voltages with different values of total harmonic distortion (THD). It is observed that CIV reduces with the increase in harmonic voltage with higher THD. Phase resolved partial discharge pattern, peak-to-peak voltage, and the energy content due to corona discharges measured by both fluorescence-based and UHF techniques follows the same trend, indicating the viability of the new technique.

Synthesis of multi-walled carbon nanotubes (MWNTs) by arc discharge in liquid nitrogen is reported. As liquid nitrogen substituted both vacuum and cooling systems, high-quality MWNTs were produced at a low cost. The content of the MWNTs can be as high as 70% of the reaction product. Auger-spectroscopy analysis revealed that no nitrogen is incorporated in the MWNTs. This method can be an economical route for the mass production of highly crystalline MWNTs.

Synthesis of copper and zinc nanostructures by discharges in liquid nitrogen

Synthesis of Cu@ZnO core–shell nanoparticles by spark discharges in liquid nitrogen

The synthesis feasibility of silicon–tin nanocrystals by discharges in liquid nitrogen is studied using a Si–10 at % Sn sintered electrode. Time-resolved optical emission spectroscopy shows that silicon and tin melt almost simultaneously. The presence of both vapours does not lead to the synthesis of alloyed nanocrystals but to the synthesis of separate nanocrystals of silicon and tin with average sizes of 10 nm. These nanocrystals are transformed into amorphous silicon oxide (am–SiO2) and β–SnO2 by air oxidation, after evaporation of the liquid nitrogen. The synthesis of an am-Si0.95Sn0.05 phase around large silicon crystals (~500 nm) decorated by β–Sn spheroids is achieved if the current flowing through electrodes is high enough. When the sintered electrode is hit by powerful discharges, some grains are heated and tin diffuses in the large silicon crystals. Next, these grains are shelled and fall into the dielectric liquid.

Nano-objects synthesized from Cu, Ag and Cu28Ag72 electrodes by submerged discharges in liquid nitrogen

Dynamics of the development of surface discharges in liquid nitrogen

Nanosecond-pulsed discharge in liquid nitrogen ignited using a needle electrode and positive 60 kV high voltage pulses was characterized using fast and shadow imaging, as well as optical emission spectroscopy. Estimation of temperature was done using molecular nitrogen emission of second positive system ro-vibrational transition spectra, and the maximum temperature increase is estimated to be ~60 K. We also report on the first observations of plasma-generated unstable material from liquid nitrogen, presumably a form of polynitrogen compound.

The synthesis of CdO, Ag2O (5 nm) and Ag (∼20–30 nm) nano-objects is achieved simultaneously by nanosecond-pulsed discharges in liquid nitrogen between one cadmium electrode and one silver electrode. Oxidation occurs when liquid nitrogen is fully evaporated and nanoparticles are in contact with the air. No alloy is formed, whatever the conditions, even though both elements are present simultaneously, as showed by time-resolved optical emission spectroscopy. This lack of reactivity between elements is attributed to the high pressure within the discharge that keeps each metallic vapor around the electrode it comes from. Each element exhibits a specific behavior. Cubic Cd particles, formed at 4 kV, get elongated with filamentary tips when the applied voltage reaches 7 and 10 kV. Cd wires are formed by assembly in liquid nitrogen of Cd nanoparticles driven by dipole assembly, and not by dielectrophoresis. On the contrary, silver spherical particles get assembled into 2D dendritic structures. The anisotropic growth of these structures is assumed to be due to the existence of pressure gradients.

Fluorescent fiber-based identification of incipient discharges in liquid nitrogen