Abstract

New emerging high-energy radiation detection techniques are based on the use of rare-earth ion doped materials. There is a great demand for new inorganic scintillators for medical applications, including X-ray and g radiation detection. In these applications, the new scintillating materials must comply with the main requirements such as high optical quality, high light yield, short response time etc. Materials satisfying these requirements include Gd3Al2Ga3O12: Ce (GAGG : Ce) scintillating single crystals. By now the optical characteristics of GAGG : Ce have been studied insufficiently. We have therefore measured the spectral reflectance and transmittance characteristics of these crystals using optical spectroscopy in the 200–750 nm range. We have also measured the absorbance and refractive indices and the extinction coefficients, and assessed the optical band gap for GAGG : Ce crystals. For measuring the refractive indices, we have used two spectrophotometric methods, i.e. by the measured Brewster angle and by the reflectance for low incidence angles, i.e., close to the normal. Based on the results we have drawn up the dispersion functions of the refractive indices.

Highlights

  • Gd3Al2Ga3O12 : Ce (GAGG : Ce) scintillating single crystals are of a great research interest because of the novelty and unique properties of this material

  • The aim of this work is to determine the optical characteristics of GAGG:Се crystals using optical spectrophotometry, including the values and dispersion dependences of the refractive indices

  • Band gap estimates for GAGG : Ce were published earlier [9, 16]. These results suggest that the band gap of GAGG : Ce is (5.8–6.8) eV

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Summary

Introduction

Gd3Al2Ga3O12 : Ce (GAGG : Ce) (gadolinium/aluminum/­ gallium garnet) scintillating single crystals are of a great research interest because of the novelty and unique properties of this material. The chemical elements of the host lattice (Gd3+, Ga3+ and Al3+) are located at the structural positions formed by coordination polyhedrons with oxygen atoms at the vertices:

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