Open time studies of cold curing polyurethane adhesives using a standardized spatula test setup suitable for near-production conditions

Abstract

The presented studies introduce a new set-up and method to analyse the maximum open time of cold curing adhesives in a production environment. By using this new set-up, a manual spatula test, Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR-FTIR) and a rheological method, the curing reaction of two cold curing two component polyurethane adhesives, were investigated. Furthermore, the effect of different joining times on the bonding behaviour were investigated using single lap shear samples.The lap shear tests showed that the prior problem for industrial applications is the dimensional accuracy rather than the adhesion to the substrates as all samples showed cohesive or substrate near cohesive failure even when joined after the maximum open time. All used methods showed a coherent curing behaviour for both adhesives. However, the derived times as well as their accuracies vary depending on the used method. Using the easy manual spatula test, the open time is determined by the sensory feelings of the testing person while pressing a wooden spatula into the adhesive bead and is often used in industrial applications. However, the accuracy lies only within 10–20 s especially for slow curing adhesives. In comparison, the ATR-FTIR method, which is based on the decrease of the isocyanate group during the reaction, showed shorter times, whereas longer times were determined by observing the complex viscosity increase of the rheological measurements. Even though the ATR-FTIR and rheological measurements showed reproducible times due to the required laboratory environment and testing procedure, they are therefore not suitable for production conditions. As the introduced new method is based on the manual spatula test, it is suitable for the production environment with the advantage of a good reproducibility. Furthermore, with this method decreasing maximum open times were observed for increasing bead cross sections.