Abstract
Double cyclometalation of planar, oligomeric phenylpyridines yielded dinuclear palladium(ii) complexes with novel out-of-plane anisotropy. An X-ray crystal structure analysis revealed that the complexes exhibit concave-convex geometry, and 1H NMR measurement evidenced the occurrence of stable out-of-plane anisotropy. The dipole moment and Pd-Pd interaction were investigated by theoretical calculations.
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