Abstract
An on-line intelligent background correction in ICP-AES using a laboratory-constructed photodiode array (PDA) spectrometer is described. The PDA spectrometer provides a very convenient way for both flexibility in choice of analytical wavelength and fast concurrent acquisition of the data required for on-line background correction. Prior knowledge of sample composition and visual inspection of the spectral window are not required. The method is evaluated by determining Al and La in Ca matrix.
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