Abstract
Photoinduced electron transfer reaction of 1,4-dicyanobenzene with allyltrimethylsilane in acetonitrile was analyzed by on-line electrospray mass spectrometry. A reductive allylation product of 1,4-dicyanobenzene was detected for the first time as a key intermediate in the photoinduced electron transfer reaction. The electrospray technique, combined with a flowing photoreaction cell, was shown to be a useful tool for detecting and identifying unstable intermediates or primary products in organic photochemical reactions.
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