Abstract

A one‐step surfactant‐free hydrothermal route is developed to prepare platelike NaNbO3 template powders. At optimal KOH concentration, pure platelike NaNbO3 with rhombohedral structure (width and thickness of 20 and 2 μm, respectively) is obtained at 200°C for 16 h. After calcination at 600°C for 4 h, the structure of the hydrothermally synthesized NaNbO3 changes from rhombohedral to orthorhombic, whereas the initial platelike morphology is maintained. Such characteristics in terms of phase structure, elemental composition, and morphology render our hydrothermally synthesized NaNbO3 suitable for textured ceramic fabrications.

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